澶嶅埗鎴愬姛
  • 鍥炬鑳屾櫙
  • 绾壊鑳屾櫙

绗旇

  • 2019-11-16
    涓哄ぇ浜哄甫鏉ュ舰璞$殑缇婄敓鑲栨晠浜嬫潵鍘 涓哄瀛愬甫鍘诲揩涔愮殑鐢熻倴鍥剧敾鏁呬簨闃呰
    璋堣皥鎬庢牱瀛﹀ソ鏁板_鑻忔闈-涓鐢熸枃搴
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涓婁紶浜庯細2015-06-17

绮変笣閲忥細25

瓒佺幇鍦ㄧ殑鍙屾墜杩樿兘鎷ユ姳褰兼锛岃秮鎴戜滑杩樿兘鍛煎惛锛屽幓瑙佷綘鎯宠鐨勪汉锛屽仛浣犳兂鍋氱殑浜嬨

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彩票快三直播—官方网址22270.COM鈥攑鍨婥u1-xNixO閫忔槑姘у寲鐗╁崐瀵间綋钖勮啘鐨勫埗澶囧強鎬ц兘鍙峰垎鏋

涓嬭浇绉垎锛1250

鍐呭鎻愮ず锛 澶嶆棪澶у纭曞+瀛︿綅璁烘枃彩票快三直播—官方网址22270.COM鈥攑鍨婥u1-xNixO閫忔槑姘у寲鐗╁崐瀵间綋钖勮啘鐨勫埗澶囧強鎬ц兘鍒嗘瀽濮撳悕锛氭柦灞曠敵璇峰浣嶇骇鍒細纭曞+涓撲笟锛氫俊鎭姛鑳芥潗鏂欎笌鍣ㄤ欢鎸囧鏁欏笀锛氬紶缇20090518 淇℃伅鍔熻兘鏉愭枡涓庡櫒浠剁澹浣嶈鏂噋Cul 锛庯紝N i 銆彩票快三直播—官方网址22270.COMo閫忔槑姘у寲鐗╁崐瀵间綋钖勮啘鐨勫埗澶囧強鎬ц兘鍒嗘瀽瑕嗘棪涓婅倗鎽樿鏈枃閲囩敤鍥烘佸弽搴旀硶鎴愬姛鍒跺浜嗚繃娓¢噾灞炴哀鍖栫墿CuO 鍜孨 i O 鐨勬贩鍚堢墿Cul 锛庛侼 i xO 闈舵潗锛屽苟棣栨浣跨敤鑴夊啿绛夌瀛愪綋娌夌Н鏂规硶(Pul sedPl asm aD eposi ti on,PPD)鍦ㄦ櫘閫氱幓鐠冭‖搴曚笂鍒跺浜嗙浉搴旂殑Cul 锛巟N i 銆侽 l +5钖勮啘銆傚鍒跺鐨勯澏鏉愪笌钖勮啘锛屽垎鍒敤Seebeck绯绘暟銆佽〃闈㈣疆寤撲华銆佸彲瑙佸厜鍒嗗厜鍏夊害璁$瓑璁惧鏂规硶娴嬭瘯鍏剁數瀛﹀拰鍏夊...

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澶嶆棪澶у纭曞+瀛︿綅璁烘枃彩票快三直播—官方网址22270.COM鈥攑鍨婥u1-xNixO閫忔槑姘у寲鐗╁崐瀵间綋钖勮啘鐨勫埗澶囧強鎬ц兘鍒嗘瀽濮撳悕锛氭柦灞曠敵璇峰浣嶇骇鍒細纭曞+涓撲笟锛氫俊鎭姛鑳芥潗鏂欎笌鍣ㄤ欢鎸囧鏁欏笀锛氬紶缇20090518 淇℃伅鍔熻兘鏉愭枡涓庡櫒浠剁澹浣嶈鏂噋Cul 锛庯紝N i 銆彩票快三直播—官方网址22270.COMo閫忔槑姘у寲鐗╁崐瀵间綋钖勮啘鐨勫埗澶囧強鎬ц兘鍒嗘瀽瑕嗘棪涓婅倗鎽樿鏈枃閲囩敤鍥烘佸弽搴旀硶鎴愬姛鍒跺浜嗚繃娓¢噾灞炴哀鍖栫墿CuO 鍜孨 i O 鐨勬贩鍚堢墿Cul 锛庛侼 i xO 闈舵潗锛屽苟棣栨浣跨敤鑴夊啿绛夌瀛愪綋娌夌Н鏂规硶(Pul sedPl asm aD eposi ti on,PPD)鍦ㄦ櫘閫氱幓鐠冭‖搴曚笂鍒跺浜嗙浉搴旂殑Cul 锛巟N i 銆彩票快三直播—官方网址22270.COMO l +5钖勮啘銆傚鍒跺鐨勯澏鏉愪笌钖勮啘锛屽垎鍒敤Seebeck绯绘暟銆佽〃闈㈣疆寤撲华銆佸彲瑙佸厜鍒嗗厜鍏夊害璁$瓑璁惧鏂规硶娴嬭瘯鍏剁數瀛﹀拰鍏夊鎬ц兘锛屽埄鐢╔RD銆丄FM 銆丼EM 绛夋墜娈靛垎鏋愬叾缁撴瀯鍜岃〃闈㈠舰璨屻彩票快三直播—官方网址22270.COM鍦ㄥ垎鏋愭祴璇曠殑鍩虹涓婂畬鎴愪簡闈舵潗鎴愬垎浼樺寲璁捐锛孭PD宸ヨ壓鍙傛暟浼樺寲璁捐鍜岄鐏鐞嗗钖勮啘鎬ц兘褰卞搷绛夋柟闈㈢殑鐮旂┒宸ヤ綔銆彩票快三直播—官方网址22270.COM閲囩敤鍥虹浉鍙嶅簲娉曞埗澶囩殑涓绯诲垪Cut锛巟N i 銆侽 闈舵潗鍦ㄥ娓╀笅鍧囦负P鍨嬪鐢点俋RD缁撴灉鏄剧ずCul 锛巟N i xO 闈舵潗鍏锋湁CuO 鍜孨 i O 鐨勬贩鍚堢浉銆侰ul 锛巟N i xO 闈舵潗鐨勭數闃荤巼闅弜鐨勫澶у厛鍑忓皬鍚庡澶э紝鍦▁>0锛9鍚庡張鍑忓皬銆傞澏鏉愭垚鍒嗕紭鍖栫粨鏋滆〃鏄嶤uo锛95N i o锛∞O 闈舵潗鐨勭數闃荤巼鏈灏忥紝涓256fl cm 銆彩票快三直播—官方网址22270.COM浣跨敤Cuo锛9sN i o锛050闈舵潗鍒跺P鍨嬫幒闀嶆哀鍖栭摐TO S钖勮啘锛庣爺绌跺彂鐜版哀姘斿帇寮恒彩票快三直播—官方网址22270.COM鍦2锛6pa涓-3锛4 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ectri cal 锛宱pti caland structureproperti esof thetargetsand fi l m s w ere characteri zedby four-probe m ethod, profi l om eter, spectrophotom eter, XRD锛孉FMand SEM 锛嶤ul -xN i xOfi l m s w eredeposi ted byPPD for the fi rst ti m e, sothe rel ati ons betw een寤縧 ei rphysi cal propm i esanddeposi ti on param etersw erei nvesti gatedi ndetai l 锛嶵he Cut锛巟N i xOtargetsexhi bi tedp-type conducti vi tyat 100mtem perature锛嶺RDtest dem onstrated the CuO and N i O m i xedphase锛嶵he com posi ti on opti m i zati onshow edthat theresi sti vi tyof theCu0锛95N i o锛0sOtargeti s the l ow est, 256Q cm 锛嶯 idopedCuOp-typeTO S thi n fi l m s w eredeposi ted涓絤theCu0锛95N i o锛050target锛嶪ti s found thatpure 02 w orki ng atm osphere, l arge w orki ng vol tage, andl owsubstrate tem perature i s goodforat roomtem perature i ncreaseddecreased as theoxygen pressurei ncreased from2锛6 Pa to 3锛4 Pa锛111eaveragevi si bl ethe p- type conducti vi ty锛嶵he conducti vi ty ofCuo锛9sN i o锛巓sO l +sfi l m sdeposi tedfi rstand 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钖勮啘浠ュ悗锛岀爺绌惰呬滑鍋氫簡杩涗竴姝ョ殑钖勮啘鍒跺鐮旂┒锛孲u绛変汉鎶ョ寤哄揩涓夋妧宸 鈥旈椤-TCa鎺烘潅SxCu202锛屽苟鍒跺Tpn缁撱愯窂銆俁0y绛夌敤婧惰兌鍑濊兌鍜岀敥鑳舵硶鍒跺浜哠A202钖勮啘锛屼负瑙勬ā鍖栫殑鍟嗕笟搴旂敤鎻愪緵浜嗗疄楠屼緷鎹901銆傝〃1锛3鏄嚑绉峉rCu202钖勮啘鐨勬暟鎹俆abl e 1-3 Theparam enter ofp-typeSrCu202TO SsM atedalM ethodT( 锛)0(S· cIn锛1)SrCu202PLD703锛9xl O -3e-beamevaporati on>605锛3x10qSrCu202锛欳aPLD>708锛2× 10—2SrCu202"KPLD804锛83x10—22銆佺悊璁虹爺绌禨rCu202鏅朵綋缁撴瀯鍜岃兘甯︾粨鏋勭ず鎰忓浘濡傚浘1锛5鎵绀恒傚畠绫讳技浜嶤u20缁撴瀯锛屽叿鏈0-Cu-O 鍝戦搩鐘剁粨鏋勶紝杩欑缁撴瀯鍗曞厓浜掔浉杩炴帴褰㈡垚娌跨潃[010銆戝拰[100]鏂瑰悜鎴愰敮榻跨姸涓缁撮摼缁撴瀯銆傝繖绉嶇粨鏋勪腑鐩搁偦Cu+dl o鐢靛瓙闂寸殑鐩镐簰浣滅敤灞闄愬湪Cu-Cu鍗曢摼鍐咃紝鏈夊埄浜庡睍瀹藉叾鍏夊绂佸甫瀹藉害锛屾彁楂橀忔槑鎬с911銆 淇℃伅鍔熻兘鏉愭枡涓庡櫒浠剁澹浣嶈鏂嘝鍨婥ul 銆侼 i Io閫忔槑姘у寲鐗╁崐瀵间綋钖勮啘鐨勫埗鍚勫強鎬ц兘鍒嗘瀽瑕嗘浖鍦熻懚鈭 缈崇攧-寮撳ⅷ鏆戝弬Fi gure1-5Crystal structure(1eft)andbandsm l cture(ri ght)ofSrCu202锛02骞碠 hta绛変汉涓嶩 osono锛廱缁勫悎浣滅爺绌朵簡S濡冧箿02鍜孲rCu202锛欿缁撴瀯锛屾寚鍑篴=0锛5469 nm 锛宑=0锛9826ni n锛屽苟鍙戠幇璁$畻寰楀埌鐨凞O S璋憋紝X灏勭嚎鍚告敹璋辨樉绀虹殑鐢靛瓙缁撴涓嶤u20鐨勭數瀛愬崄鍒嗙浉浼硷紝鍥犳鎻愬嚭浜嗙敤Cu20鐨勭數瀛愮粨鏋勮В閲奡rCu202鐨勭數瀛愮粨鏋勶紝濡傚浘1-6鎵绀猴細Fi gure 1-6 Il l ustrati on of the el ectroni c structure ofCu20锛宐asi cal l yappl i cabl e to that of SCO 锛嶣ands I’ II, III’ andIV aretentati vel yl abel edanti -bondi ngstate of Ca and O 锛孨 onbondi ngstate ofCu锛孨 onbondi ngstate ofCu, N onbondi ngstate ofO 锛宎ndBondi ngstateof Cuand O 锛嶯 i e绛夌敤鍩轰簬绗竴鎬у師鐞嗙殑LDA鍜孴B锛嶭M TO 鍒嗗埆瀵筍rCu202甯︾粨鏋勮繘琛屼簡璁$畻锛屼粬浠涓篠rCu202鐨勪环甯︾敱O2p鍜孋! u3d鏉傚寲缁勬垚涓斾环甯﹂《涓昏鏉l Cu锛屽苟杈僀u20鍏锋湁鏇寸獎鐨勪环甯﹀搴︼紝p鍨嬪鐢垫潵fl Cu3d1鍟921銆備粠鍘熷瓙涔嬮棿鐩镐簰浣滅敤鍑哄彂锛孊oudi nS绛夊氨CuAl Ch鍜孲rCu202鐨勭數瀛愮粨鏋勮繘琛屼簡姣旇緝锛屽彂鐜拌櫧鐒朵簩鑰呯殑鑳藉甫缁撴瀯闈炲父绫讳技鍗磋〃鐜板嚭鏄庢樉涓嶅悓鐨勫鐢电壒鎬( 濡傜數瀵肩巼CuAl 02杈僑rCu202澶) 锛岀敱US6‘2O2 姝ゅぇ鑳嗚瀹氭槸浠峰甫椤剁殑Cu 3d鐢靛瓙鍙婂叾鐩镐簰浣滅敤瀵圭數瀛︽ц兘璐熻矗銆931銆侽 hta绛変粠鐞嗚鍜屽疄楠屼笂瀵筍rCu202鐨勫厜鐢垫ц兘杩涜浜嗙爺绌讹紝鍏夌數瀛愯兘璋( XPS鍜孶 PS) 鏄剧ず璇ョ墿璐ㄧ殑绂佸甫Eg=3锛3eV锛屼笌鍚告敹鍏夎氨寰楀埌鐨勭粨鏋滃惢鍚堛侻 odrem u鍦07骞村彂琛ㄧ殑鏂囩珷涔熻瘉瀹炰簡涓婅堪瑙傜偣‘ 941銆1锛2锛4鎺烘潅ZnO鎺烘潅ZnO 鏄竴绉嶅崄鍒嗛噸瑕佺殑p鍨婽O S钖勮啘锛岀敱浜巒-ZnO 鏉愭枡寰堝锛屼笖寰楀埌浜嗗簲鐢紝濡俍nO 锛欼n锛廇1锛廎锛廈锛廏at95銆97銆戯紝濡傛灉鑳藉鍒跺tBp-ZnO 锛屽垯鍙互鍒跺鍚岃川pn缁擄紝涓洪忔槑鐢靛瓙瀛︾殑瀹炵幇甯︽潵宸ㄥぇ绐佺牬锛屽洜姝-ZnO 鐨勭爺绌跺彈鍒板箍娉涘叧娉ㄣ俵 銆佽杽鑶滄潗鏂欑爺绌剁敱浜嶼nO 鍙椾富鐨勫浐婧跺害杈冧綆锛岃屼笖ZnO 涓殑璇稿浣庤兘鏈緛鏂戒富缂洪櫡( 闂撮殭Zn鍜屾哀绌轰綅) 浼氫骇鐢熼珮搴︾殑鑷ˉ鍋挎晥搴旓紝娣辩殑鏉傝川鑳界骇涔熶細闃绘褰㈡垚娴呭彈涓昏兘绾э紝鎵浠nO 鐨刾鍨嬫幒鏉傚崄鍒嗗洶闅惧, 991銆傛渶鏃╁埗澶噋锛巣nO 鐨勫皾璇曟槸鎺烘潅N 鍜岃垻銆恖 O O -1021銆傝繎骞存潵锛屽熀浜庣涓鎬у師鐞嗙殑璁$畻锛孻am am oto绛変汉鎻愬嚭灏嗘柦涓讳笌鍙椾富鏉傚織鍏辨嫸103銆戯紝骞剁敱J oseph绛夋垚鍔熷疄鐜般1041锛屽緱鍒拌杽鑶滅殑閫忓皠鐜囪秴杩80锛呫傞櫎姝や箣澶栵紝N 鍕樺叡鎺恒1鍚层丯 锛庣牕鍏辨幒銆106-109]锛孲b鎺烘潅绛変篃鏈夋姤绂忓缓蹇笁鎶宸 鈥旈椤-銆恑 10]銆傝〃1锛4鏄嚑绉峆鍨嬫幒鏉俍nO 钖勮啘鐨勬暟鎹俆abl e 1-4 Theparam enter ofp-type dopedZnOTO SsM ateri alM ethodT(锛)O ( S· cm -1)ZnO 锛歂 锛嶨 aReacti ve RFM S902ZnO 锛歂 锛嶪nU SP59ZnO 锛歂 锛嶢lD CRM S901锛7x10-2涓鈼廌 C>854x10-2RFM S>80lZnO 锛歅PLD5锛9x 10-2M O CVD909锛8x10-2ZnO 锛歋bM BE5FVAD7ZnO 锛欰sPLDZnO 锛歂M BE0锛025ZnO 锛歂 锛嶣M SO 锛42Zno锛9M go锛巌O 锛歂 —A1D CRM S903锛9xl O -2· 锛宯l efi l m s w el ' epreparedby gaseousam m oni aanneal i ng 淇℃伅鍔熻兘鏉愭枡涓庡櫒浠剁澹浣嶈鏂嘝鍨媍ul -l N i l 0閫忔槑姘у寲鐗╁崐瀵间綋钖勮啘鐨勫埗鍚勫強鎬ц兘鍒嗘瀽瑕嗚澶т簨鈻犫枲鈻燺鈻燺鈼忊枲鈻燺鈻燺鈻犫棌鈼忊枲鈼忊棌_鈻犫枲鈻燺___鈻燺鈻犫棌鈻犫棌鈼廮鈼忊棌__鈻犫棌鈻犫枲_鈼忊枲鈻燺鈼忊枲鈼忊枲鈻犫枲鈻犫枲鈻犫枲鈼忊棌鈻犫枲鈼廮鈼忊枲鈼廮鈻犫枲鈻燺鈻犫棌鈼忊枲__鈼忊枲_鈼忊枲鈻犫棌鈼忊棌鈻犫枲鈼廮鈻犫枲涓1——————涓——————鈰1鈼忊棌鈼忊枲鈻燺2銆佺悊璁虹爺绌禮am am oto绛変汉鏍规嵁绗竴鎬у師鐞嗚绠椾簡znO 鐨勭數瀛愮粨鏋勩1031锛孡ei 绛変汉瀵筃 鎺烘潅ZnO 杩涜-f"Ram an鍒嗘瀽銆1111锛孻u绛変汉妯℃嫙璁$畻TZnO 涓己闄风殑鐘舵併1121锛屽苟鎻愬嚭zIl O鍙互鍦ㄤ竴涓緢绐勭殑姘у師瀛愭瘮渚嬬獥鍙e唴琛ㄧ幇鍑虹ǔ瀹氱殑p鍨嬪鐢点俍nO 鏅朵綋缁撴瀯鍜岃兘甯︾粨鏋勭ず鎰忓浘濡傚浘1锛7鎵绀恒傗棁 VB锛硷紟JL锛巬闇逛笂f鍝ワ紟锛‘r7g锛庤搫Il锛況t锛庡绋斾簩锛庯紡姘愶紝l锛糂Fi gure1-7 U ni t cel l of thecrystalstructure ofZnO (1eft)锛嶵he l i ght grey spheres con' gspondstooxygen锛宼hedark O nes to zi nc锛嶵hepri m i ti vetransl ati on vectors a and b i ncl ude閿刟ngl eof 1200 and a∞si tuatedi nthe basepl ane锛宑i sorthogonalto themTheval enceband( va) andconducti onband( CB) of ZnO ( ri ght) i nthevi ci ni 鍖唎fthefundam ental bandgap锛1锛2锛5姘х~鏃忓寲鍚堢墿姘х~鏃忓寲鍚堢墿P鍨嬮忔槑瀵肩數鏉愭枡鐨勫寲瀛﹂氬紡涓篖nCuO Q ( Ln=闀х郴鍏冪礌La銆丳r銆丯 d锛決 =纭棌鍏冪礌S銆丼e銆乀e) 銆傚叾缁撴瀯涓庨摐閾佺熆鐩镐技涓哄眰鐘剁粨鏋勶紝鐢( Ln202)2+鍜( Cu2Q 2) 2‘ 涓ゅ眰娌縞杞翠氦鏇垮爢鍨涜屾垚銆俵 銆佽杽鑶滄潗鏂欑爺绌剁幇鍦ㄤ富瑕佺爺绌剁殑姘х~鏃忓寲鍚堢墿鏈塋aCuO S銆丩aCuO Se銆丩aCuO l 鍤稴ex銆丅aCu2S2銆丅aCu2Q F绛夈俇 eda K绛夐噰鐢ㄥ弽搴旂鎺ф簠灏勬硶鎴愬姛鍒跺LaCuO S钖勮啘锛岃瘉瀹炲畠鏄疨鍨嬪崐瀵间綋銆1131銆傚湪La浣嶆幒鏉傚皯閲廠r鍚庯紝鐢变簬sP鏇夸唬鍙+锛岀數瀵肩巼鎻愰珮浜嗙害20鍊嶃侶i ram atsu绛変汉鐮旂┒浜哃aCuO SI锛巟Sex浣撶郴涓璖e鍚噺瀵瑰叾瀵肩數鎬ц兘鐨勫奖鍝嶃114銆戙傚綋鍦↙aCuO Se鎺篈M g鍚庤杽鑶滅殑鐢靛鐜囦负140Scm 涓銆2009骞碒 i ram atsu绛変汉鎶ョ寤哄揩涓夋妧宸 鈥旈椤-璇︾粏浠嬬粛浜嗗绉嶅眰鐘舵哀纭寲鐗╋紝骞朵粙缁嶄簡鍏跺簲鐢ㄣ1151銆傝〃1锛5鏄嚑绉峆鍨嬫哀纭棌鍖栧悎鐗╄杽楝诲槻¨ _ 淇℃伅鍔熻兘鏉愭枡涓庡櫒浠剁澹浣嶈鏂噋鍨媍u銆傘侼 i xo閫忔槑姘у寲鐗╁崐瀵间綋钖勮啘鐨勫埗澶囧強鎬ц兘鍒嗘瀽妫嬫棪鎴堣懚鑶滅殑鏁版嵁銆俆abl e 1-5 Theparam enter ofp-tYl 鈪猳xychal cogeni deTO Ssconducti vi tyM ateri alM ethodT( 锛)(S· cm -1)( LaO ) CuSr锛庯俊sputteri ng701锛2x10-2(Lal -xSrxO )CuSr锛庯俊sputteri ng702锛6x10-I( LaO ) CuSe10SPE24(LaO )CuSe锛歁 g10SPE140R锛嶴PE910BaCu2S2RFM S90172銆佺悊璁虹爺绌剁悊璁虹爺绌惰〃鏄庣浉姣旂瀛愬瀷锛忓叡浠峰瀷姘у寲鐗╋紝纭哀鍖栧悎鐗㎜nCuQ 涓璔 鐨刵p(搴3)鑳界骇鍜孋h3d鏇村姞鎺ヨ繎锛屾潅鍖栧悗缁勬垚浠峰甫椤( VBM ) 锛屽悓鏃跺叿鏈墄锛寉鏂瑰悜鏇村ぇ鐨勫悇鐩稿紓鎬э紝绌虹┐鍦ㄥ眰鍐呬紶杈撴洿鍔犺嚜鐢憋紝鍥犳LnCuQ 浣撶郴鐨勫鐢甸斿緞鏇村姞鍚堢悊锛屽鐢垫т篃鏇村ソ銆侺a锛庯紝’ 鈭 銆傦紟tO 鑿囬槼h濞溿侰u锛(1鐭+Fi gure 1-8 Crystalstructur楣fl ayered O xychal cogeni de LaCuO Ch( Ch=chal cogcn) 锛( 1eft)l atti ce system 锛歵etragonal 锛宻pace group锛歅4锛弉m m 鐢渙锛129)锛嶦nergybanddi agramand thetotal 锛弍ar6alD O S of LaCuO S near the Ferm ienergy(m i ddl e)andthebandoffset at the C锛嶣锛巃ndV锛嶣锛(ri ghO 锛庡眰鐘剁殑姘х~鍖栧悎鐗㎜aCuO Ch( Ch=S锛孲e锛孴e) 鏅朵綋缁撴瀯濡傚浘1锛8鎵绀猴紝LaCuO Ch灞炰簬鍥涙柟鏅剁郴缁撴瀯锛屽叾绌洪棿缇や负P4锛弉m m 銆1-8涓棿鍜屽彸杈瑰浘鍒嗗埆鏄疞aCuO S鐨勭數瀛愯兘甯︾粨鏋勶紝Ferm i 鑳界骇闄勮繎褰掍竴鍖栫殑DO S鍜屼环甯︼紡瀵煎甫绀烘剰鍥俱傚浘1锛9鏄眰鐘舵哀纭棌鍖栧悎鐗╃殑鍒嗗瓙绀烘剰鍥惧拰娌垮師瀛愯建绂忓缓蹇笁鎶宸 鈥旈椤-閲嶅彔鏂瑰悜鐨勮兘甯︾粨鏋勭ず鎰忓浘銆傜爺绌惰〃鏄嶤u鐨勮精鈻燜q銆侊技椴紝&鍙攖銆傚悾鍕 淇℃伅鍔熻兘鏉愭枡涓庡櫒浠剁澹浣嶈鏂噋鍨媍u銆傘侼 i l 0閫忔槑姘у寲鐗╁崐瀵间綋钖勮啘鐨勫埗澶囧強鎬ц兘鍒嗘瀽瑕嗘殤涓婅懚3dl o涓庣~鏃忓師瀛愮殑p6杞ㄧ寤哄揩涓夋妧宸 鈥旈椤-鏉傚寲瀵瑰舰鎴恜鍨嬪鐢佃捣鍒伴噸瑕佷綔鐢ㄣ1161銆傦紝锛岃眮鐢忛強*’ 锛*锛岋紡6锛=锛歽g鏅2}涔=Fi gure1-9 Schem ati c m ol ecul ardi agramofoxychal cogeni des(1eft)andschem ati cena' gybanddi agramal ongw i th theoverl apof atom i corbi tal s(ri ght)锛嶵hecati ons w i thl argesOorbi tal s arei ndi spensabl e forn- typeconducti on and thehybri di zati onofchal cogen( Ch) p6and Cu 3dw orbi tal s i svi talforp-typeconducti on todi spersetheconducti on锛弙al ence band or to formconducti onpathsi ncrystal s锛1锛3P鍨婽O S钖勮啘鐨勫簲鐢ㄩ殢鐫瓒婃潵瓒婂鍏夌數鎬ц兘鑹ソ鐨凱鍨嬮忔槑瀵肩數钖勮啘鐨勪骇鐢燂紝浣垮緱鐪熸瀹炵幇閫忔槑鐢靛瓙瀛︽垚涓哄彲鑳姐傚叾涓紝鏈绠鍗曠殑鐢靛瓙鍣ㄤ欢灏辨槸鍏锋湁鏁存祦鏁堝簲鐨勮杽鑶滀簩鏋佺pn缁撱傝櫧鐒堕忔槑钖勮啘浜屾瀬绠$殑缁撴瀯绠鍗曪紝浣嗘槸鐢变簬鍙互鐢ㄤ簬瀹炵幇“ 鍔熻兘绐” 绛夊櫒浠讹紝鍦ㄩ忓皠澶槼鍏変腑鍙鍏夌殑鍚屾椂灏嗙传澶栫嚎鍚告敹锛屽洜姝ゅ叾鎰忎箟涓庝綔鐢ㄥ崄鍒嗛噸澶с傚彟澶栬杽鑶滃満鏁堝簲鏅朵綋绠( TFET) 锛岀传澶栧彂鍏変簩鏋佺锛岀瓑涔熸湁鎶ョ寤哄揩涓夋妧宸 鈥旈椤-銆1锛3锛1閫忔槑钖勮啘浜屾瀬绠ato绛夈35銆戦娆¢噰鐢≒鍨婲 i O 鍜宯鍨媄nO 锛欰I鎴愬姛鍒跺浜嗗崐閫忔槑鐨刾锛巌 -n鍨嬭杽鑶滀簩鏋佺锛屽叾缁撴瀯涓簆-N i O 锛廼 锛嶯 i O 锛廼 锛嶼nO 锛弉锛嶼nO 锛欰I锛孭鍨嬪眰鍜宯鍨嬪眰鐨勫帤搴﹀垎鍒负195am 鍜400am 锛岀數瀛︽祴璇曡〃鐜板嚭鐨勬暣娴佹晥搴旇瘉鏄庡叾鍏锋湁浜屾瀬绠℃ц兘銆傝櫧鐒朵粬浠張灏濊瘯杩囩敤p-N i O 鍜11锛嶼nO 锛欰I鍒跺p-n鍨嬭杽鑶滀簩鏋佺锛屼絾鍏舵鍙嶅悜鐢垫祦鐢靛帇鏇茬嚎閮藉憟鐩寸嚎锛屽苟鏈垚鍔熴備笌姝ょ被浼硷紝KudoA绛夈19J 鍒╃敤n-ZnO 涓巔-SrCu202鎴愬姛鍒跺浜嗗叏閫忔槑鐨刾-n鍨嬪紓璐ㄧ粨銆傚垎鍒娇鐢╪-ZnO 鍜孭锛嶴rCu202浣滀负n鍨嬩笌P鍨嬪眰涓昏鏄洜涓轰簩鑰呬箣闂村尮閰嶇殑鏅舵牸缁撴瀯锛屽悓鏃惰緝浣庣殑SrCu202鍒跺娓╁害涔熻兘澶熷噺灏戜簩鑰呯晫闈㈤棿鐨勫寲瀛﹀弽搴斻 鐒︽槦鐮栬兘鎷辩涓庡櫒浠剁澹浣嶉伩P鍨婥ut銆侼il0閫忔槑姘у寲鐗╁崐瀵间綋钖勮啘鐨勫埗澶囧強鎬ц兘鍒嗘瀽浼嶇殗涓婃搸SC0poh—i m 鈪猠鈻 o锠 绾涒枲 -zI璞炽侀湼璞‘IIJ Zo銆9·鍛恛銆6锛003·I锛-锛庘嫰锛· 15-3锛1135Bi asVol tage(銆侊紝)Fi gurel‘ 10銆恆)Structureofatransparenthetero-j uncti ondi odeoftheform 锛歡l ass锛廔TO 锛弍-SrC' u202锛弉-ZnO 锛弉+-ZnO 锛庡槥Recti fyi ng I-V characteri sti csofp- nhetero-j uncti onas show ni n(a)鍏跺櫒浠剁粨鏋勫拰I锛嶸鐗规ф洸绾垮鍥1锛10鎵绀恒傝杽鑶滀负澶氭櫠鏉愭枡锛屾诲帤搴︾害1300Im 锛屼粠(b)鍥惧彲浠ョ湅鍑哄畠鍏锋湁鑹ソ鐨勬暣娴佺壒鎬э紝姝e弽鍚戠數娴佹瘮杈80锛屽彲瑙佸厜骞冲潎閫忓皠鐜囦负70锛咃綖80锛呫備粬浠繕鍒跺浜唒-SrCu202锛欿锛廼 锛嶼nO 锛弉-ZnO 缁撴瀯鐨刾-i 锛巒寮傝川缁撱371锛岃岀浉搴旂殑Hoffm an绛夈38銆戝埗澶囦簡n+锛嶪TO 锛廼 锛嶼nO 锛弍+-CuY02锛欳a缁撴瀯pi -n鍨嬫哀鍖栫墿鍏ㄩ忔槑寮傝川缁撲簩鏋佺锛屽帤搴︿负750 ri m 锛屽湪娉㈤暱400"700 nm鍐咃紝閫忓皠鐜囧湪35"-' 65锛呬箣闂淬傚叿鏈夋槑鏄剧殑鏁存祦鐗规э紝鏂藉姞4-4 V鍋忓帇锛屽叾姝e弽鍚戠數娴佹瘮楂樿揪60銆傜爺绌跺彂鐜板彲浠ラ氳繃璋冭妭娌夌Н杩囩▼涓殑姘ф皵鍒嗗帇鏉ユ敼鍙榋nO 钖勮啘涓殑杞芥祦瀛愭祿搴︽潵鍖归厤SrCu202涓殑绌虹┐娴撳害锛屽洜姝-CuYn锛庛侰a, Ch( x=O 锛01锝0锛02)锛弉-Znl 锛巟Al xO (x=0锛02)缁撴瀯鐨刾-n鍨嬪紓璐ㄧ粨涔熸湁鎵鎶ョ寤哄揩涓夋妧宸 鈥旈椤-銆391锛屽叾寮鍚數鍘嬪湪0锛4"--' 0锛8V涔嬮棿銆俆onooka绛夈40銆戞姤绂忓缓蹇笁鎶宸 鈥旈椤-鐨刵锛嶼nO 锛弍-CuAl 02缁撴瀯浜屾瀬绠″湪锛1锛5锝1锛5V闂叿鏈90鐨勬鍙嶅悜鐢垫祦姣旓紝鍙鍏夊钩鍧囬忓皠鐜囦篃杈惧埌40锛, --锛70锛咃紝鑰屼笖鍏锋湁鍏変紡鏁堝簲銆傜敱浜庡悓璐ㄧ粨鑳藉鑷姩鍦拌В鍐虫櫠鏍煎尮閰嶉棶棰橈紝鍥犳閫忔槑鍚岃川缁撳惛寮曚簡骞挎硾鐨勫叧娉ㄣ俌anagi 绛変汉銆4l 銆戠涓涓姤绂忓缓蹇笁鎶宸 鈥旈椤-浜嗗叏閾滈搧鐭跨粨鏋勭殑p-n鍚岃川缁擄紝缁撴瀯涓篩SZ(111)IITO l p-CuIn02锛欳a锛弉锛嶤uIn02锛歋n锛廔TO 锛岃瀵熷緱鍑哄畠鐨勫紑鍚數鍘嬩负1锛8eV锛屽彲瑙佸厜閫忓皠鐜囦负60锝80锛呫侫oK锛忕瓑浜恒42銆戝埗澶囦簡p-ZnO 锛欰s锛弉-ZnO 锛欰l 鍜宲-ZnO 锛歅锛弉锛嶼nO 鍚岃川缁撱侶w 閿刧绛変汉銆43銆戞姤绂忓缓蹇笁鎶宸 鈥旈椤-浜唍锛嶼nO 锛弍-ZnO 锛欰s鐨勯忔槑鍚岃川缁擄紝寮鍚數鍘嬩负2锛5 V銆俆uzem en绛夈愬垹鎶ョ寤哄揩涓夋妧宸 鈥旈椤-浜嗙敤鍙嶅簲浜ゆ祦纾佹帶婧呭皠娉曪紝閫氳繃鎺у埗姘ф癌娣峰悎姘斾綋涓殑姘у垎鍘嬪垎鍒埗澶噋-ZnO 鍜宯-ZnO 骞跺舰鎴愬悓璐ㄧ粨鐨勫皾璇曘侭i an绛変汉145銆戝埗澶囦簡p-ZnO 锛歂 锛孖n锛弉-ZnO 浜屾瀬绠°侸 ang绛変汉銆461閲囩敤P鎵╂暎鑾峰緱p-ZnO 锛歅锛屽埗澶囧嚭p-ZnO 锛歅锛廧nO 浜屾瀬绠★紝鏂藉姞+3锛忎竴5 V鐢靛帇鏃讹紝姝e弽鍚戠數娴佹瘮绾︿负70锛屾浠琒)o鍒犺亙 鍫★紝鍨﹀爼鑳芥潗鏂欎笌鍣ㄤ欢纭曞+瀛︿綅璁烘枃P鍨婥ut銆侼 i 銆俹閫忔槑姘у寲鐗╁崐瀵间綋钖勮啘鐨勫埗澶囧強鎬ц兘鍒嗘瀽缁勬棪涓婁簨鍚戝紑鍚數鍘嬩负4V銆俍huge绛変汉銆471鎶ョ寤哄揩涓夋妧宸 鈥旈椤-浜唒-ZnO 锛欰I, N 锛弉-ZnO 锛欰I缁撴瀯鐨勪簩鏋佺锛屽紑鍚數鍘嬩负2V銆侸 i ao绛変汉銆48銆戞姤绂忓缓蹇笁鎶宸 鈥旈椤-浜唒-ZnO 锛歂 锛弉-ZnO 鍙戝厜浜屾瀬绠★紝姝e悜寮鍚數鍘嬫槸4V锛岀數鑷村彂鍏変綅浜庡叞绱尝闀垮尯鍩熴俌e鍦╬-ZnO 鏂归潰宸ヤ綔寰堢獊鍑猴紝鍥1-11鏄粬浠渶鏂板彂琛ㄧ殑ZnO 鍩哄悓璐╬Il 缁撶殑缁撴瀯鍥惧拰锛-V鏇茬嚎銆49銆戙侳i gurel 锝1 t- V characteri sti cs of then-ZnO 锛弉-Z锛巒o锛巃Cdo锛20锛弍-ZnO di ode锛嶭efti nset show sschem ati cal l ythe cro, 鎴硄 secti on of theheteroj uncti on锛寃 hereas ri ghti nset show sO hm i c contacts oftheInZnal l oyO l i then· andp-ZnO 锛宺especti vel y锛庡浜庡叏ZnO 閫忔槑浜屾瀬绠$粨鏋勶紝濡傛灉鑳藉浼樺寲娌夌Н宸ヨ壓浣胯浇娴佸瓙娴撳害杩涗竴姝ユ彁楂橈紝灏嗕細寮鍒涢忔槑鐢靛瓙瀛︾殑鏂板眬闈€傝〃l 鐭虫荤粨浜嗚繎骞存潵閫忔槑浜屾瀬绠$殑鐮旂┒鐘跺喌銆俆abl e 1-6Param eters of sel ectedtransparentdi odesD i ode s鍜朿tllIIcSubstratep-fi l mn锛巉i l mi -fi l mp{鈪猽nG l assN i OZnO 锛欰1N i Q 浜縩Op锛弉G l assS鐤媢202ZnOp锛弉YSZ( 111)SrCu202ZnOIl锛忓搏G l assCuY02锛欳al TOZnOp锛弉YSZ( 111)CuIn02锛欳aCuIn02锛歋np锛弉GaAs(001)ZnO 锛欰sZnOp锛弉Si (100)ZnO 锛歂 锛嶪nZnOp锛弉quartzZnO 锛歂 锛庤垻ZnO 锛欰1p锛弉a-A1203ZnO 锛歂ZnOp锛弉P—Si (111)ZnO 锛歂 锛嶢1Zno锛巗Cdo锛20 淇℃伅鍔熻兘鏉愭枡涓庡櫒浠剁澹浣嶈鏂噋鍨媍ul 锛嶪N i 銆俹閫忔槑姘у寲鐗╁崐瀵间綋钖勮啘鐨勫埗澶囧強鎬ц兘鍒嗘瀽姊楁棪涓婅懚1锛3锛2钖勮啘鍦烘晥搴旀櫠浣撶閫忔槑钖勮啘鍦烘晥搴旀櫠浣撶(TransparentFi el d锛巈ffect Transi stor锛孴FET)鏄忔槑鐢靛瓙瀛﹀彟涓涓噸瑕侀鍩熴傜敱浜庢湁鏁堟矡绂忓缓蹇笁鎶宸 鈥旈椤-灞(Acti veChannel Layer)鍏锋湁瀹藉甫闅欙紝TFET瑁搁湶鍦ㄥ彲瑙佸厜涓嬬壒鎬у苟涓嶈“鍑忥紝鑰岄潪鏅剁鍜屽鏅剁Tl 涓屼細鍙戠敓琛板噺銆傚洜姝ゅ疄鐜癟FET瀵规湭鏉ラ忔槑鐢靛瓙瀛﹀湪澶槼鑳界數姹犻鍩熺殑搴旂敤鍏锋湁閲嶈鐨勬剰涔夈侾ri ns绛変汉pl 銆戞姤绂忓缓蹇笁鎶宸 鈥旈椤-浜嗗熀浜嶴n02锛歋b钖勮啘鐨勯搧鐢礣FET锛屽叾鍦烘晥搴旇縼绉荤巼绾︿负10cm 2V-1s-1锛屽紑鍏崇數娴佹瘮涓104銆侶 offi nan绛変汉銆52銆戞姤绂忓缓蹇笁鎶宸 鈥旈椤-浜嗛珮閫忔槑ZnO -TFET锛涙爡缁濈紭灞傛槸閾濋挍姘у寲鐗( ATO ) 锛孖TO 鐢ㄤ綔鏍呫佹簮鍜屾紡鐢垫瀬锛孼nO 鍏呭綋娌熺寤哄揩涓夋妧宸 鈥旈椤-灞傦紝闃堝肩數鍘嬪拰鍣ㄤ欢鐨勬矡绂忓缓蹇笁鎶宸 鈥旈椤-杩佺Щ鐜囧垎鍒槸10"-20 V鍜0锛3锝2锛5 cm 2V"1s锛嶪锛屽紑鍏崇數娴佹瘮绾︿负107锛屽寘鎷幓鐠冨熀鏉跨殑鍣ㄤ欢鍙鍏夐忓皠鐜囬珮杈75锛呫侻 asuda绛変汉銆53銆戞姤绂忓缓蹇笁鎶宸 鈥旈椤-浜哯nO -TFET锛孲i 02鍜孲i N x鍙屽眰缁撴瀯浣滀负鏍呯粷缂樺眰锛岃繖绉嶅弻灞傜粨鏋勬湁鍒╀簬鎶戝埗婕忕數娴侊紝鍦烘晥搴旇縼绉荤巼鍜岀數娴佸紑鍏虫瘮鍒嗗埆涓簂cm 2V-1s-1鍜宭 O s锛屽彲瑙佸厜閫忓皠鐜囧ぇ浜80锛呫侰arci a绛塱 s4] 鎶ョ寤哄揩涓夋妧宸 鈥旈椤-鐨刏nO -TFET鍦烘晥搴旇縼绉荤巼鍜岀數娴佸紑鍏虫瘮鍒嗗埆涓2cm 2V-1s浠ュ拰106锛屽彲瑙佸厜閫忓皠鐜囧ぇ浜80锛呫侰hi ang绛変汉銆55銆戝埗澶囦簡闈炴櫠閿岄敗姘у寲鐗㏕FET锛屽彲瑙佸厜閫忓皠鐜囦负84锛咃紝鍣ㄤ欢缁300鈩冨拰600鈩冪儹澶勭悊鍚庯紝鍣ㄤ欢鐨勫満鏁堝簲杩佺Щ鐜囧垎鍒负5"15鍜20"--50 cm 2V-1s锛1锛岀數娴佸紑鍏虫瘮楂樿揪10銆傘侱ehuff绛変汉銆56銆戞姤绂忓缓蹇笁鎶宸 鈥旈椤-浜哯IO ( ZnO 鍜孖n203鐨勬懇灏旀瘮涓2锛1) TFET锛屽櫒浠剁殑鍙鍏夐忓皠鐜囬珮杈85锛咃紝鍣ㄤ欢缁忓悗澶勭悊锛屾矡绂忓缓蹇笁鎶宸 鈥旈椤-杩佺Щ鐜囪揪鍒45"--' 55 cm 2V"1s锛1锛岀數娴佸紑鍏虫瘮涓106銆侻 i yasako绛変汉銆57銆戝埗澶囩殑ITO -TFET锛庡叾涓爡缁濈紭灞備负閾佺數BkL姘愯タ3012(BLT)钖勮啘锛屽満鏁堝簲杩佺Щ鐜囧拰鐢垫祦寮鍏虫瘮鍒嗗埆涓9锛1 cm 2V-1s锛1鍜104锛屽敖绠″叿鏈変綆鐨勫満鏁堝簲杩佺Щ鐜囷紝浣咺TO 锛廈LT缁撴瀯鐨凾l 鍙湁鐫杈冨ぇ鐨勬紡鐢垫祦( 2锛5 m A) 锛岃繖鍙兘鏄敱浜庨搧鐢佃杽鑶滆嚜鍙戞瀬鍖栬鑷村ぇ鐨勭數鑽峰瘑搴︺侹i m 绛変汉銆58銆戦噰鐢ㄩ珮浠嬬數甯告暟Bi l 锛5Znl 锛0N bl 锛507(BZN )钖勮啘涓烘爡缁濈紭灞傜殑ZnO -TFET锛400 nm 浠ヤ笂娉㈤暱鐨勯忓皠鐜囧ぇ浜80锛咃紝鍦烘晥搴旇縼绉荤巼鍜岀數娴佸紑鍏虫瘮鍒嗗埆涓篛 锛024 cra2V-1s锛1鍜2xl o锛庯紝闃堝肩數鍘嬩负2 V銆侼 om w a绛変汉銆59銆戦噰鐢≒LD鎶鏈垚鍔熺殑鍒跺浜嗗叏閫忔槑姘у寲鐗╄杽鑶滄櫠浣撶銆傚叾缁撴瀯涓哄崟鏅禮SZ( III) J b鍩烘澘锛屽崟鏅舵哀鍖栫墿InGa03( ZnO ) 5( IGZO ) 浣滀负鍩哄簳鐨勬湁鏁堥氭矡绂忓缓蹇笁鎶宸 鈥旈椤-锛岄潪鏅舵哀鍖栫墿H f02浣滀负鏍呯粷缂樺眰锛孖TO 鐢ㄤ綔婧愩佹紡鍜屾爡鐢垫瀬锛涚粡娴嬭瘯鍣ㄤ欢鍦ㄦ尝闀390"--3200 nm 鑼冨洿鍐呭钩鍧囬忓皠鐜囧ぇ浜80锛咃紱鐢垫祦寮鍏虫瘮绾︿负106锛屽満鏁堝簲杩佺Щ鐜囬珮杈80cm 2V-鍗淪1銆傚皢80ri m 鍘氱殑闈炴櫠H fO x灞傜敤浣滅粷缂樻爡灞傦紝ITO 鐢ㄤ綔婧愩佹紡鍙婃爡鐢垫瀬鐨勭粨鏋勶紝鍏堕忓皠鐜囬珮杈捐繎100锛咃紟婕忕數娴佸湪10"gA閲忕骇锛岀數娴佸紑鍏虫瘮瓒呰繃105銆侽 hm 绛変汉鎶ョ寤哄揩涓夋妧宸 鈥旈椤-鐨勯忔槑鏈夋満钖勮啘鏅朵綋绠°愬彨锛屽熀鏉块噰鐢╕SZ011) 鍗曟櫠锛400 ri m 鍘氱殑(Sco锛7Yo锛3)03鐢ㄤ綔楂榢鏍呯粷缂樺眰锛屾簮銆佹紡鍜屾爡鐢垫瀬鍧囦负l i fO 锛岀敤鍒嗗瓙鏉熷寤舵柟娉曞埗澶囩殑40 nm 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閫氳繃钂稿彂鎴栧崌鍗庝娇琚晙鏉愭枡姘斿寲锛2)灏嗗師瀛愭垨鍒嗗瓙杈撹繍鍒板熀鏉胯〃闈紱3) 涓婅堪绮掑瓙娌夌Н浜庡熀鏉夸笂锛4) 涓婅堪绮掑瓙鍦ㄥ熀鏉胯〃闈㈤噸鏂版帓鍒楋紝褰㈡垚钖勮啘銆傝繖绉嶆柟娉曞叿鏈夌粨鏋勭畝鍗曪紝钖勮啘绾害楂橈紝鍦ㄤ竴瀹氱▼搴︿笂鍙互杈惧埌棰勬湡鐨勮杽鑶滅粨鏋勭殑浼樼偣銆傜湡绌鸿捀鍙戦晙鑶滄妧鏈富瑕佸寘鎷湡绌哄弽搴旇捀鍙戞硶( VacuumReacti veEvaporati on锛歏RE)锛岀垎鐮村紡钂稿彂(expl odi ngw i reevaporati on) 锛岃剦鍐叉縺鍏夋潫娌夌Н( Pul seLaserDeposi ti on锛歅LD) 鍜屽垎瀛愭潫澶栧欢( M BE) 銆傝繖浜涙柟娉曟槸鏍规嵁涓嶅悓鐨勫弽搴斿師鐞嗗拰鐗╃悊銆佸寲瀛﹁繃绋嬪埗澶囪杽鑶滄潗鏂欙紝鍏锋湁鍚勮嚜鐨勭壒鐐瑰拰搴旂敤棰嗗煙銆傛湰閮ㄥ垎鍐呭瀵瑰悇绉嶇湡绌洪晙鑶滄妧鏈殑鍘熺悊鍋氫竴涓畝鍗曟弿杩般1锛4锛1鐩存祦婧呭皠鎶鏈洿娴佹簠灏勬妧鏈槸婧呭皠闀鑶滀腑璁惧缁撴瀯姣旇緝绠鍗曠殑鎶鏈傝婧呭皠鏉愭枡鍋氶槾鏋侊紝鍩烘澘鍋氶槼鏋併傜洿娴佹簠灏勫彧鑳戒娇鐢ㄥ浣撴潗鏂欎綔涓洪澏鏉愶紝杩欐槸鐢变簬鍦ㄥ彈鍒版绂诲瓙杞板嚮鍚庯紝缁濈紭鏉愭枡闈舵潗琛ㄩ潰浼氱Н绱鐢佃嵎锛屽鍚庣户鐨勮桨鍑荤瀛愪骇鐢熸帓鏂ヤ綔鐢紝鏈缁堝鑷存斁鐢靛仠姝€ 1, 4锛2灏勯婧呭皠鎶鏈皠棰戞簠灏勬妧鏈彲浠ヨВ鍐崇洿娴佺鎺ф簠灏勬妧鏈殑杩欎竴闂銆傚皠棰戞簠灏勯噰鐢ㄥ皠棰戠數婧...

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